Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes.
نویسندگان
چکیده
Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in continuous gas-phase. The reaction protocol is exemplified for the decarbonylation of p-tolualdehyde to toluene and further extended to other aromatic and aliphatic aldehydes achieving excellent results in terms of both conversion and selectivity.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 46 شماره
صفحات -
تاریخ انتشار 2014